Rozantsev G. Polyoxometalate-anions of d-elements of V and VI groups in a solution and in the salts

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0513U000540

Thesis Registration Form

0513U000540.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

27-05-2013

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The thesis is devoted to the development of a common approach to the creating of the optimal techniques of synthesis of the salts with polyoxometalate anions of V and VI groups on the basis of the study of their behaviour in a solution. The concentration and thermodynamic constants of the reactions and standard thermodynamic functions of formation were calculated, fundamentally new sequence-parallel schemes of mutual transitions are proposed. The areas of each ionic form domination are revealed on the basis of the diagrams of distribution. This was taken into account while creating the techniques of the synthesis140 new salts.

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Files

aref.doc

aref.doc

dis.pdf

pril.doc

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