Martsinko E. Coordination and supramolecular chemistry of complex germanium(IV), tin(IV) anions with complexons and hydroxycarboxylic acids

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0514U000072

Thesis Registration Form

0514U000072.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

30-01-2014

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

In the dissertation the regularities of the formation of anionic complexes of germanium(IV), tin(IV) with complexons and hydroxycarboxylic acids, the possibility of their use as metalotektons for the synthesis of 139 new mono-, di-, oligo- or polymeric coordination compounds with the ions of s-, d-, f-metals and organic molecules (exogenous ligands), held their classification by structure types. For the first time a comparative analysis of the structure of germanium (IV) and tin (IV) with mono- and diaminokarboxylic complexons. Patented compound with 1-hydroxyetilendiphosphonic-, tartaric-, xylaric- and bis(citrate)germanium (tin) anions as effective pharmaceutical agents.

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Files

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aref.doc

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