Shved O. Acidolysis and phenolysis of epichlorohydrin catalysed organic bases

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0515U000359

Thesis Registration Form

0515U000359.pdf

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

14-05-2015

Specialized Academic Board

Д 08.078.03

Ukrainian State University of Chemical Technology

Essay

The thesis has proposed the unificated mechanism of the acidolysis and phenolysis of epichlorohydrin catalysed by organic bases: tertiary amines, pyridines, tetraalkyl ammonium halides and carboxylates. This work has proposed the kinetic models suitable for prediction of reactivity of nucleophiles in such reactions.. The approbation of this models was carried out by comparing the calculated characteristics with experimental data. The new regularitys are the base for improvement of known methods of syntheses of epoxy materials.

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Files

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aref.doc

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