Vretik L. The selectivity in the polymerization of monomers bearing several double bonds

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0515U000796

Thesis Registration Form

0515U000796.pdf

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

06-10-2015

Specialized Academic Board

Д 26. 001. 25

Essay

The thesis is devoted to the development of scientific and practical bases of synthesis for alken-functionalized photoactive polymers by radical polymerization of monomers with double bonds of different reactivities. The conditions were found for preferable polymerization of methacrylate group with the formation of poly(phenyl/ naphthylmethacrylates) with free tetrahydrophthalimide, maleimide or methacrylamide side groups. The definitive role of Fries photorearrangement in the origine of photoinduced optical anisotropy was proved for films of the synthesised alken-functionalised polymers. The perspectivity of developed polymers was described as photoalignment layers of liquid crystals.

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