Lampeka Y. Redox reactions of tetragonal nickel(III,II), copper(III,II) and cobalt(III,II) with polydentate nitrogen containing ligands

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0599U000061

Thesis Registration Form

0599U000061.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

06-04-1999

Specialized Academic Board

Д26.190.01

Essay

Nickel, copper and cobalt complexes with macrocyclic and non cyclic amines. To establish the relationships between the structure of the complexes and thermodynamic and kinetic aspects of their redox behaviour. The spectral (IR, absorption, EPR, NMR), electrochemical, photochemical and kinetic methods were used. The approaches to control the redox potentials and reactivity of metal complexes were developed. The catalysts for photooxidation of methanol, chain transfer from polymer to monomer and inhibitors of oxidation of organic compounds were proposed. Application area is metallocomplex catalysis.

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