Semenyshyn D. Cyanide complexes of transition metals with Nitrogen- and Oxygen-containing compounds

Thesis is devoted to the synthesis and physico-chemical investigation of cyanide complexes of transition metals with Nitrogen- and Oxygen- containing compounds in external and internal spheres. Composition of complexes and the way of ligand coordination have been established. The influence of the nature of Nitrogen- and Oxygen-containing organic cations, ligands, metal-complexings on cyanide complexes structure has been evaluated. The crystal structure of three typical cyanide complexes representatives has been investigated. The succession of physico-chemical processes taking place during thermal decomposition of cyanide complexes has been determined. The general reregularities of their thermolysis have been formulated. The possibility of practical application of cyanide complexes for inhibitor protection of steel have been shown