Shelyakin V. Cyclization reactions of the functionally sub-stituted 1,3-dicarbonyl compounds heterocyclic row with cyanoacetic acide derivatives

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0404U000144

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

25-12-2003

Specialized Academic Board

Д. 26.217.01

Essay

. The reactions of 1,3-dicarbonyl compounds of heterocyclic row were investigated for the first time considering steric position of 1,3-dicarbonyl function and cyanoacetic acid derivatives in them. Convenient methods of the functionally substituted oxygen-, nitrogen-, silfur-containing heterocyclic compounds synthesis were elabo-rated at reactions of 1,3-dicarbonyl heterocyclic row compounds. New stable heterocyclic row sulfides were synthesized, including those which contain electron-acceptor substituents in their structure, 3-aminothiophenes were obtained ay their base including those which are annelated with isoquinoline, cyclopenta[c]pyridine, 1,6-naphtiridine, 5-alkyl-6-(2-thienyl)-pyridine cycles.

Files

Similar theses