Glukh A. The synthesis and reactions of aminoquinones and those derivatives

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0407U005095

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

09-11-2007

Specialized Academic Board

Д 08.078.03

Ukrainian State University of Chemical Technology

Essay

The object – 2,5dyaryl(alkyl)amino-4-(aryl)imido-1,4-benzoquinones, 2-arylamino-1,4-benzoquinones 2,5dyaryl(alkyl)amino-1,4-benzoquinones; purpose - investigation of synthesis and reactivity of aryl(alkyl)aminobenzoquinones, first of all, their cyclisations; novelty - 2-(p-Tolylamino)-3-[N-(p-tolylimido)]-8-methylphenoxazine has been obtained. The general scheme of interplay of 2,5-dy(aryl)amino-4-(aryl)imido-1,4-benzoquinones with N-(p-tolyl)-1,4-benzoquinonemonoimide has been offered first tame. The processes of interplay of aromatic and aliphatic amines with 1,4-benzoquinone has been investigated. The common rules of these reactions have been clearly recognized. The kinetics of addition of aromatic amines to 1,4-benzoquinone have been investigated.

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