Hutych Y. Spectroscopic diagnostics of formation of II-VI semiconductor nanocrystals in dielectric matrices

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U005070

Applicant for

Specialization

  • 01.04.10 - Фізика напівпровідників і діелектриків

06-11-2009

Specialized Academic Board

К 61.051.01

Essay

Optical spectroscopic techniques are applied for the diagnostics of formation and characterization of II-VI nanocrystals in glass matrices. The increase of heat treatment temperature or duration is shown to result in the increase of the predominant chalcogen content in CdS1-xSex ternary nanocrystals. Quaternary Cd1-yZnyS1-xSex and CdS1-x-ySexTey, semiconductor nanocrystals of two-mode and three-mode phonon spectrum transformation type, respectively, were synthesized. It is shown that beyond the optimal heat treatment parameter interval a possible alternative to the formation of CdSe-type nanocrystals is formation of Se2 clusters in the borosilicate glass.

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