Ryabinina A. Researching of the cellulose destruction under the sulphuric acid influence and development the compositions for giving acid-proof application to textile materials

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0408U003740

Applicant for

Specialization

  • 05.18.19 - Технологія текстильних матеріалів, швейних і трикотажних виробів

19-06-2008

Specialized Academic Board

Д 67.052.02

Essay

Subject of the research is the process of giving the acid-proof properties to the textile materials. The object of the research is creation the compositions for giving to the cellulosecontaining textile materials the acid-proof application. Research methods are: viscosimetric, iodinemetric, alkali hydrolyses, Rebinder's, Kyeldal's, IR-spectroscopy. Intensification action of methylsiliconate of kalium in dyeing processes is determined at first time. The character of cellulose destruction of fabrics, applicated by protecting compositions on the base of GKJ-11K, that present in the fraction contain changing aside decrease of lowmolecular fractions by the means of it's hydrolyse and solution is determined firstly. It is found, that for getting the textile materials with stabile to soup-sodium processing acid-proof effect, it is necessary that the compounds, entering in the finishing preparation contain, form on the fibre elastic protecting film, not changing whole of their structure under the chemical andphysical-mechanic influence, and also hold on the fibre by the chemical bonds, at that their quantity and alternation are decisive. It is found, that using of amincontaining silicone and GKJ-11K by the means of creation of alkaline midst result to aminogroup injunction and formation of chemical bond between the hydroxyl groups of cellulose and reaction siloxane. Introduction of worked out compositions is planned in the textile industry.

Files

Автореферат_Рябинина.doc

Автореферат_Рябинина.doc

Диссертация_Рябинина--01 Титульный лист.doc

Диссертация_Рябинина--01 Титульный лист.doc

Диссертация_Рябинина--02 Содержание.doc

Диссертация_Рябинина--02 Содержание.doc

Диссертация_Рябинина--03 Условные обозначения.doc

Диссертация_Рябинина--03 Условные обозначения.doc

Диссертация_Рябинина--04 Введение.doc

Диссертация_Рябинина--04 Введение.doc

Диссертация_Рябинина--05 Лит.обзор.doc

Диссертация_Рябинина--06 Метод.часть.doc

Диссертация_Рябинина--06 Метод.часть.doc

Диссертация_Рябинина--07 Подраздел 3.1..doc

Диссертация_Рябинина--07 Подраздел 3.1..doc

Диссертация_Рябинина--08 Подраздел 3.2..doc

Диссертация_Рябинина--08 Подраздел 3.2..doc

Диссертация_Рябинина--09 Подраздел 3.3..doc

Диссертация_Рябинина--09 Подраздел 3.3..doc

Диссертация_Рябинина--10 Выводы.doc

Диссертация_Рябинина--10 Выводы.doc

Диссертация_Рябинина--11 Титул_приложений.doc

Диссертация_Рябинина--12 Приложение_А_Ранжирование.doc

Диссертация_Рябинина--13 Приложение Б.doc

Диссертация_Рябинина--14 Приложение В.doc

Диссертация_Рябинина--15 Список лит-ры.doc

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